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It was only available inside random booster packs of the SM8a Dark Order series that was released in Japan, in October, 2018

The new item will feature 2 promo cards, one each of Blaziken ex and Vlcanion ex

Despite this card not being as tooth-pullingly rare as it is in the anime its pretty common, in fact it has a lot of rare reprints in both modern and retro packs, as well as a ton of alt art that makes it a prized card for serious collectors

Alternatively, you can win with Felidar Sovereign or Angel of Destiny, which will win you the game if you have a certain threshold of life, something easily done with how much life can be gained